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Synthesis and characterization of luminescent polyfluorenes incorporating side-chain-tethered polyhedral oligomeric silsesquioxane units

dc.citation.epage751en_US
dc.citation.issue3en_US
dc.citation.spage745en_US
dc.citation.volume38en_US
dc.citation.woscount117
dc.contributor.authorChou, CHen_US
dc.contributor.authorHsu, SLen_US
dc.contributor.authorDinakaran, Ken_US
dc.contributor.authorChiu, MYen_US
dc.contributor.authorWei, KHen_US
dc.contributor.department材料科學與工程學系zh_TW
dc.contributor.departmentDepartment of Materials Science and Engineeringen_US
dc.date.accessioned2014-12-08T15:19:43Z
dc.date.available2014-12-08T15:19:43Z
dc.date.issued2005-02-08en_US
dc.description.abstractUsing Suzuki polycondensation, we have synthesized polyhedral silsesquioxane-tethered polyfluorene copolymers, poly(9,9'-dioctylfluorene-co-9,9'-bis[4-(N,N-dipolysilsesquioxane)aminophenyl]fluorene) (PFO-POSS), that have well-defined architectures. This particular PFO-POSS molecular architecture increases the quantum yield of polyfluorene significantly by reducing the degree of interchain aggregation; in addition, these copolymers exhibit a purer and stronger blue light by preventing the formation of keto defects.en_US
dc.identifier.doi10.1021/ma0479520en_US
dc.identifier.issn0024-9297en_US
dc.identifier.journalMACROMOLECULESen_US
dc.identifier.urihttp://dx.doi.org/10.1021/ma0479520en_US
dc.identifier.urihttps://ir.lib.nycu.edu.tw/handle/11536/14007
dc.identifier.wosnumberWOS:000226764500017
dc.language.isoen_USen_US
dc.titleSynthesis and characterization of luminescent polyfluorenes incorporating side-chain-tethered polyhedral oligomeric silsesquioxane unitsen_US
dc.typeArticleen_US

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