Synthesis and dielectric properties of polyimide-tethered polyhedral oligomeric silsesquioxane (POSS) nanocomposites via POSS-diamine
| dc.citation.epage | 9127 | en_US |
| dc.citation.issue | 24 | en_US |
| dc.citation.spage | 9122 | en_US |
| dc.citation.volume | 36 | en_US |
| dc.citation.woscount | 145 | |
| dc.contributor.author | Leu, CM | en_US |
| dc.contributor.author | Chang, YT | en_US |
| dc.contributor.author | Wei, KH | en_US |
| dc.contributor.department | 材料科學與工程學系 | zh_TW |
| dc.contributor.department | Department of Materials Science and Engineering | en_US |
| dc.date.accessioned | 2014-12-08T15:40:00Z | |
| dc.date.available | 2014-12-08T15:40:00Z | |
| dc.date.issued | 2003-12-02 | en_US |
| dc.description.abstract | Polyimide-tethered polyhedral oligomeric silsesquioxane, (R7R'Si8O12) (POSS), nanocomposites with well-defined architectures are prepared by the copolymerization reaction of a new type of diamine monomer: POSS-diamine, 4,4'-oxydianiline (ODA), and pyromellitic dianhydride (PMDA). This type of polyimide-side-chain-tethered POSS nanocomposite presents self-assembly characteristics when the amount of POSS exceeds 10 mol %, as evidenced by transmission electron microscopy studies. Furthermore, POSS/polyimide nanocomposites have both lower and tunable dielectric constants, with the lowest value of 2.3, and controllable mechanical properties, as compared to that of pure polyimide. | en_US |
| dc.identifier.doi | 10.1021/ma034743r | en_US |
| dc.identifier.issn | 0024-9297 | en_US |
| dc.identifier.journal | MACROMOLECULES | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1021/ma034743r | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/27326 | |
| dc.identifier.wosnumber | WOS:000186857700028 | |
| dc.language.iso | en_US | en_US |
| dc.title | Synthesis and dielectric properties of polyimide-tethered polyhedral oligomeric silsesquioxane (POSS) nanocomposites via POSS-diamine | en_US |
| dc.type | Article | en_US |