Synthesis of 4-oxo- and 4-anti-formyl-8,10,12,13-tetraoxapentacyclo[5.5.1.0(2,6).0(3,11).0(5,9)]tridecanes
| dc.citation.epage | 17668 | en_US |
| dc.citation.issue | 52 | en_US |
| dc.citation.spage | 17653 | en_US |
| dc.citation.volume | 53 | en_US |
| dc.contributor.author | Wu, HJ | en_US |
| dc.contributor.author | Chern, JH | en_US |
| dc.contributor.department | 交大名義發表 | zh_TW |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | National Chiao Tung University | en_US |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:01:14Z | |
| dc.date.available | 2014-12-08T15:01:14Z | |
| dc.date.issued | 1997-12-29 | en_US |
| dc.description.abstract | The synthesis of 4-oxo- and 4-anti-formyl-8,10,12,13-tetraoxapentacyclo[5.5.1.0(2,6).0(3,11).0(5,9)]tridecanes has been accomplished. Ozonolysis of compounds 10a,b and 12a-c in dichloromethane at -78 degrees C followed by reduction with dimethyl sulfide gave the title compounds, 4-oxo-tetraoxa-cages 11a,b and 14a-c, in moderate yields. Ozonolysis of the endo-syn isomers 15a,b and 18a,b under the same reaction conditions gave 4-anti-formyl-tetraoxa-cages 17a,b and 20a,b, respectively. (C) 1997 Published by Elsevier Science Ltd. | en_US |
| dc.identifier.doi | 10.1016/S0040-4020(97)10228-9 | en_US |
| dc.identifier.issn | 0040-4020 | en_US |
| dc.identifier.journal | TETRAHEDRON | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1016/S0040-4020(97)10228-9 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/136 | |
| dc.language.iso | en_US | en_US |
| dc.title | Synthesis of 4-oxo- and 4-anti-formyl-8,10,12,13-tetraoxapentacyclo[5.5.1.0(2,6).0(3,11).0(5,9)]tridecanes | en_US |
| dc.type | Article | en_US |