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Intramolecular Diels-Alder reaction of furans with allenyl ethers followed by phenylthio and trialkylsilyl groups rearrangement

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dc.citation.epage797en_US
dc.citation.spage789en_US
dc.citation.volume45en_US
dc.citation.woscount4en_US
dc.contributor.authorChuang, CTen_US
dc.contributor.authorYen, CHen_US
dc.contributor.authorWu, HJen_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.date.accessioned2019-04-02T05:58:59Z
dc.date.available2019-04-02T05:58:59Z
dc.date.issued1998-12-01en_US
dc.description.abstracta new reaction involving an intramolecular Diels-Alder reaction of a furan diene with an allenyl ether dienophile followed by phenylthio group rearrangement was discovered. Treatment of the propargyl ethers 2a-c with t-BuOK in t-BuOH at 85 degrees C gave the phenylthio group rearrangement products 5a-c and 6a-c. A reaction involving an intramolecular Diels-Alder reaction of a furan diene with an allenyl ether dienophile followed by trialkylsilyl group rearrangement is also demonstrated.en_US
dc.identifier.doi10.1002/jccs.199800119en_US
dc.identifier.issn0009-4536en_US
dc.identifier.journalJOURNAL OF THE CHINESE CHEMICAL SOCIETYen_US
dc.identifier.urihttp://dx.doi.org/10.1002/jccs.199800119en_US
dc.identifier.urihttps://ir.lib.nycu.edu.tw/handle/11536/148124
dc.identifier.wosnumberWOS:000077788100013en_US
dc.language.isoen_USen_US
dc.subjectintramolecular Diels-Alder reactionen_US
dc.subjectfuransen_US
dc.subjectallenyl ethersen_US
dc.subjectphenylthio group rearrangementen_US
dc.subjecttrialkylsilyl group rearrangementen_US
dc.titleIntramolecular Diels-Alder reaction of furans with allenyl ethers followed by phenylthio and trialkylsilyl groups rearrangementen_US
dc.typeArticleen_US

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