Observation of transition state in Raman triggered oxidation of chloroform in the ground state by real-time vibrational spectroscopy
| dc.citation.epage | 426 | en_US |
| dc.citation.issue | 4-6 | en_US |
| dc.citation.spage | 421 | en_US |
| dc.citation.volume | 457 | en_US |
| dc.citation.woscount | 9 | |
| dc.contributor.author | Iwakura, Izumi | en_US |
| dc.contributor.author | Yabushita, Atsushi | en_US |
| dc.contributor.author | Kobayashi, Takayoshi | en_US |
| dc.contributor.department | 電子物理學系 | zh_TW |
| dc.contributor.department | Department of Electrophysics | en_US |
| dc.date.accessioned | 2014-12-08T15:12:09Z | |
| dc.date.available | 2014-12-08T15:12:09Z | |
| dc.date.issued | 2008-05-27 | en_US |
| dc.description.abstract | A transition state (TS) during Raman triggered oxidation of chloroform was directly observed by ultrafast spectroscopy using broadband visible sub-5 fs pulses. Changes in the molecular structures including the TSs along the reaction pathways were detected by the time-dependent instantaneous frequencies of vibrational modes. The Raman triggered oxidation of chloroform was found to be initiated by the excitation of vibrational levels through stimulated Raman processes involving the ground-state chloroform oxygen complex. (C) 2008 Published by Elsevier B.V. | en_US |
| dc.identifier.doi | 10.1016/j.cplett.2008.03.003 | en_US |
| dc.identifier.issn | 0009-2614 | en_US |
| dc.identifier.journal | CHEMICAL PHYSICS LETTERS | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1016/j.cplett.2008.03.003 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/9320 | |
| dc.identifier.wosnumber | WOS:000255953800029 | |
| dc.language.iso | en_US | en_US |
| dc.title | Observation of transition state in Raman triggered oxidation of chloroform in the ground state by real-time vibrational spectroscopy | en_US |
| dc.type | Article | en_US |