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Origin of size effect on superconductivity in (R-0.8 Pr-0.2)Ba2Cu3O7 studied by soft X-ray absorption spectroscopy

dc.citation.epage91en_US
dc.citation.issue1-3en_US
dc.citation.spage85en_US
dc.citation.volume337en_US
dc.citation.woscount3
dc.contributor.authorChen, JMen_US
dc.contributor.authorNachimuthu, Pen_US
dc.contributor.authorLin, JYen_US
dc.contributor.authorHong, IPen_US
dc.contributor.authorChang, CFen_US
dc.contributor.authorYang, HDen_US
dc.contributor.department物理研究所zh_TW
dc.contributor.departmentInstitute of Physicsen_US
dc.date.accessioned2014-12-08T15:44:01Z
dc.date.available2014-12-08T15:44:01Z
dc.date.issued2001-03-30en_US
dc.description.abstractO K-edge X-ray absorption near-edge structure (XANES) spectroscopy of (R-0.8 Pr-0.2)Ba2Cu3O7 (R = Y, Tm, Dy, Gd, Eu and Sm) has been performed to investigate the dependence of hole distribution on ionic size of the R3+ ions. Near the O Is absorption edge, pre-peaks at similar to 527.8 and similar to 528.5 eV are assigned to transitions into O 2p hole states located in the CuO3 ribbons and CuO2 planes, respectively. As deduced from O K-edge X-ray absorption spectra, the hole concentrations in the CuO2 planes decrease monotonically with increasing ionic size of the rare-earth elements. The present XANES results clearly demonstrate that the suppression of superconductivity in (R1-x Pr-x)Ba2Cu3O7 With ionic radius of the R3+ ions results predominantly from the hole-depletion effect. (C) 2001 Elsevier Science B.V. All rights reserved.en_US
dc.identifier.doi10.1016/S0009-2614(01)00122-1en_US
dc.identifier.issn0009-2614en_US
dc.identifier.journalCHEMICAL PHYSICS LETTERSen_US
dc.identifier.urihttp://dx.doi.org/10.1016/S0009-2614(01)00122-1en_US
dc.identifier.urihttps://ir.lib.nycu.edu.tw/handle/11536/29758
dc.identifier.wosnumberWOS:000167818900014
dc.language.isoen_USen_US
dc.titleOrigin of size effect on superconductivity in (R-0.8 Pr-0.2)Ba2Cu3O7 studied by soft X-ray absorption spectroscopyen_US
dc.typeArticleen_US

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