TAUTOMERIC RELAXATION RATES IN THE GROUND-STATE OF TETRA-4-TERTIARY BUTYLPHTHALOCYANINE IN SHPOLSKII MATRICES

dc.citation.epage	806	en_US
dc.citation.issue	4	en_US
dc.citation.spage	797	en_US
dc.citation.volume	50	en_US
dc.citation.woscount	1
dc.contributor.author	CHEN, WH	en_US
dc.contributor.author	GAO, J	en_US
dc.contributor.author	RIECKHOFF, KE	en_US
dc.contributor.author	VOIGT, EM	en_US
dc.contributor.department	電子物理學系	zh_TW
dc.contributor.department	Department of Electrophysics	en_US
dc.date.accessioned	2014-12-08T15:04:02Z
dc.date.available	2014-12-08T15:04:02Z
dc.date.issued	1994-04-01	en_US
dc.description.abstract	We report experimental results of the ground state proton tunneling rate constant k in the absence of radiation to be from 0.03 to 0.35 s-1 at temperatures from 4.2 to 77 K for tetra-4-tertiary butylphthalocyanine tautomers embedded in hexadecane matrices. While a detailed microscopic description of the exact transfer mechanism is not possible from the data obtained so far, we present a model based on a new type of potential barrier and use the semiclassical WKB approximation to calculate transmission data compatible with experiment.	en_US
dc.identifier.issn	0584-8539	en_US
dc.identifier.journal	SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY	en_US
dc.identifier.uri	https://ir.lib.nycu.edu.tw/handle/11536/2544
dc.identifier.wosnumber	WOS:A1994MZ84000015
dc.language.iso	en_US	en_US
dc.title	TAUTOMERIC RELAXATION RATES IN THE GROUND-STATE OF TETRA-4-TERTIARY BUTYLPHTHALOCYANINE IN SHPOLSKII MATRICES	en_US
dc.type	Article	en_US

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