NMR-STUDY OF EPSILON-CAPROLACTAM IN VARIOUS SOLVENTS - GRAPHICAL DETERMINATION OF MONOMER SHIFT, DIMER SHIFT AND DIMERIZATION CONSTANT FROM THE DILUTION SHIFT DATA
| dc.citation.epage | 720 | en_US |
| dc.citation.issue | 5 | en_US |
| dc.citation.spage | 717 | en_US |
| dc.citation.volume | 90 | en_US |
| dc.citation.woscount | 21 | |
| dc.contributor.author | CHEN, JS | en_US |
| dc.contributor.department | 交大名義發表 | zh_TW |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | National Chiao Tung University | en_US |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:04:05Z | |
| dc.date.available | 2014-12-08T15:04:05Z | |
| dc.date.issued | 1994-03-07 | en_US |
| dc.description.abstract | A graphical method for the simultaneous determination of the monomer shift, dimer shift and dimerization constant of a self-association system from the dilution NMR shift data is proposed. This method avoids the conventional extrapolation to infinite dilution to obtain the monomer shift. Three self-association systems: epsilon-caprolactam in [H-2(1)]chloroform, [H-2(3)]acetone and [H-2(3)]acetonitrile were studied at various temperatures. The enthalpy and entropy of dimerization were also determined from van't Hoff plots. | en_US |
| dc.identifier.doi | 10.1039/FT9949000717 | en_US |
| dc.identifier.issn | 0956-5000 | en_US |
| dc.identifier.journal | JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1039/FT9949000717 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/2585 | |
| dc.identifier.wosnumber | WOS:A1994NB14000006 | |
| dc.language.iso | en_US | en_US |
| dc.title | NMR-STUDY OF EPSILON-CAPROLACTAM IN VARIOUS SOLVENTS - GRAPHICAL DETERMINATION OF MONOMER SHIFT, DIMER SHIFT AND DIMERIZATION CONSTANT FROM THE DILUTION SHIFT DATA | en_US |
| dc.type | Article | en_US |