Miscibility and hydrogen-bonding behavior in organic/inorganic polymer hybrids containing octaphenol polyhedral oligomeric silsesquioxane
| dc.citation.epage | 10829 | en_US |
| dc.citation.issue | 35 | en_US |
| dc.citation.spage | 10821 | en_US |
| dc.citation.volume | 112 | en_US |
| dc.citation.woscount | 30 | |
| dc.contributor.author | Yen, Ying-Chieh | en_US |
| dc.contributor.author | Kuo, Shiao-Wei | en_US |
| dc.contributor.author | Huang, Chih-Feng | en_US |
| dc.contributor.author | Chen, Jem-Kun | en_US |
| dc.contributor.author | Chang, Feng-Chih | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:10:56Z | |
| dc.date.available | 2014-12-08T15:10:56Z | |
| dc.date.issued | 2008-09-04 | en_US |
| dc.description.abstract | In this study, we Investigated the miscibility behavior and mechanism of interaction of poly(methyl mechacrylate) (PMMA), poly(vinyl pyrrolidone) PVP, and PMMA-co-PVP blends with octa(phenol)octasilsequioxane (OP-POSS). For the PMMA/OP-POSS binary blend, the value of the association constant (K(A) = 29) was smaller than that in the poly(vinyl phenol) (PVPh)/PMMA (K(A) = 37.4) and ethyl phenol (EPh)/PMMA (K(A) = 101) blend systems, implying that the phenol groups of the OP-POSS units in the PMMA/OP-POSS blends interacted to a lesser degree with the C=O groups of PMMA than they did in the other two systems. In addition, the ionic conductivity of a LiClO(4)/PMMA-co-PVP polymer electrolyte was increased after blending with OP-POSS. | en_US |
| dc.identifier.doi | 10.1021/jp8030495 | en_US |
| dc.identifier.issn | 1520-6106 | en_US |
| dc.identifier.journal | JOURNAL OF PHYSICAL CHEMISTRY B | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1021/jp8030495 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/8367 | |
| dc.identifier.wosnumber | WOS:000258800300012 | |
| dc.language.iso | en_US | en_US |
| dc.title | Miscibility and hydrogen-bonding behavior in organic/inorganic polymer hybrids containing octaphenol polyhedral oligomeric silsesquioxane | en_US |
| dc.type | Article | en_US |