Ultrafast Vibronic Processes in a Ru-Porphyrin Complex
| dc.citation.epage | 4860 | en_US |
| dc.citation.issue | 31 | en_US |
| dc.citation.spage | 4856 | en_US |
| dc.citation.volume | en_US | |
| dc.citation.woscount | 4 | |
| dc.contributor.author | Iwakura, Izumi | en_US |
| dc.contributor.author | Yabushita, Atsushi | en_US |
| dc.contributor.author | Kobayashi, Takayoshi | en_US |
| dc.contributor.department | 電子物理學系 | zh_TW |
| dc.contributor.department | Department of Electrophysics | en_US |
| dc.date.accessioned | 2014-12-08T15:10:44Z | |
| dc.date.available | 2014-12-08T15:10:44Z | |
| dc.date.issued | 2008-11-01 | en_US |
| dc.description.abstract | The excited-state dynamics of Ru(II) (TPP) (CO) (acetone) (TPP = tetraphenylporphyrin) was investigated by using a sub-5-fs pulse, In previous studies, the fluorescence lifetime of Ru(II)-(TPP)(CO) could not be resolved and was reported to be <1 ps. Analysis of the six-coordinate complexes of Ru(II)(TPP)(CO)(acetone) showed that (1)Q(x)(pi,pi*) had a lifetime of 140 +/- 20 fs and the lifetime of (3)(d,pi*) was 560 +/- 150 fs. Stimulated emission due to a spin-forbidden transition from (3)(pi,pi*) to the ground state was observed for the first time. (C) Wiley-VCH Verlag GmbH & Co. KGdA, 69451 Weinheim, Germany, 2008) | en_US |
| dc.identifier.doi | 10.1002/ejic.200800532 | en_US |
| dc.identifier.issn | 1434-1948 | en_US |
| dc.identifier.journal | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1002/ejic.200800532 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/8215 | |
| dc.identifier.wosnumber | WOS:000261049700003 | |
| dc.language.iso | en_US | en_US |
| dc.subject | Ruthenium | en_US |
| dc.subject | Photochemistry | en_US |
| dc.subject | Luminescence | en_US |
| dc.subject | Femtochemistry | en_US |
| dc.subject | Laser spectroscopy | en_US |
| dc.title | Ultrafast Vibronic Processes in a Ru-Porphyrin Complex | en_US |
| dc.type | Article | en_US |