Kinetic isotope effect on the proton-transfer in indigo carmine
| dc.citation.epage | 357 | en_US |
| dc.citation.issue | 4-6 | en_US |
| dc.citation.spage | 354 | en_US |
| dc.citation.volume | 484 | en_US |
| dc.citation.woscount | 10 | |
| dc.contributor.author | Iwakura, Izumi | en_US |
| dc.contributor.author | Yabushita, Atsushi | en_US |
| dc.contributor.author | Kobayashi, Takayoshi | en_US |
| dc.contributor.department | 電子物理學系 | zh_TW |
| dc.contributor.department | Department of Electrophysics | en_US |
| dc.date.accessioned | 2014-12-08T15:07:35Z | |
| dc.date.available | 2014-12-08T15:07:35Z | |
| dc.date.issued | 2010-01-07 | en_US |
| dc.description.abstract | We have found that photo-excited indigo carmine causes stepwise proton transfer to generate mono-alcohol intermediate, which immediately returns to the parent molecule [I. Iwakura, A. Yabushita, T. Kobayashi, Chem. Lett. 38 (2009) 1020]. The kinetic isotope effect in the proton transfer of this system has been studied by direct observation of the real-time molecular vibrational amplitude during the reaction including the transition state using a sub-5-fs laser pulse. The k(a)(H)/k(a)(D) ratio for the proton transfer after photo-excitation is observed to be 1.5 +/- 0.1. (C) 2009 Elsevier B.V. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.cplett.2009.11.029 | en_US |
| dc.identifier.issn | 0009-2614 | en_US |
| dc.identifier.journal | CHEMICAL PHYSICS LETTERS | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1016/j.cplett.2009.11.029 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/5980 | |
| dc.identifier.wosnumber | WOS:000273051800053 | |
| dc.language.iso | en_US | en_US |
| dc.title | Kinetic isotope effect on the proton-transfer in indigo carmine | en_US |
| dc.type | Article | en_US |