Structural amendment and stereoselective synthesis of mutisianthol
| dc.citation.epage | 3369 | en_US |
| dc.citation.issue | 10 | en_US |
| dc.citation.spage | 3365 | en_US |
| dc.citation.volume | 62 | en_US |
| dc.contributor.author | Ho, TL | en_US |
| dc.contributor.author | Lee, KY | en_US |
| dc.contributor.author | Chen, CK | en_US |
| dc.contributor.department | 交大名義發表 | zh_TW |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | National Chiao Tung University | en_US |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:01:46Z | |
| dc.date.available | 2014-12-08T15:01:46Z | |
| dc.date.issued | 1997-05-16 | en_US |
| dc.description.abstract | cis-1-(5-Acetoxy-3,6-dimethyl-1-indanyl)-2-methyl-1-propene synthesized from 3,6-dimethyl-1-indanone was found to be different from mutisianthol by spectral comparison. The presence of a high-field signal in the NMR spectrum of the final product and various intermediates, characteristic of the cis-1,3-dialkylindanes but absent in the spectrum of the natural terpene, suggests a revision of the structure of mutisianthol to the trans isomer. The trans-indane which was subsequently obtained indeed exhibits data fully agreeable with mutisianthol. A similar stereochemical revision for jungianol is also indicated. | en_US |
| dc.identifier.doi | 10.1021/jo970073+ | en_US |
| dc.identifier.issn | 0022-3263 | en_US |
| dc.identifier.journal | JOURNAL OF ORGANIC CHEMISTRY | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1021/jo970073+ | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/534 | |
| dc.language.iso | en_US | en_US |
| dc.title | Structural amendment and stereoselective synthesis of mutisianthol | en_US |
| dc.type | Article | en_US |