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Nanosecond Time-resolved Infrared Spectra and Structure of the Charge-transfer State of 9,9 '-Bianthryl in Acetonitrile

dc.citation.epage654en_US
dc.citation.issue6en_US
dc.citation.volume41en_US
dc.citation.woscount0
dc.contributor.authorAsami, Nobuyukien_US
dc.contributor.authorYabumoto, Sohshien_US
dc.contributor.authorShigeto, Shinsukeen_US
dc.contributor.authorTakaya, Tomohisaen_US
dc.contributor.authorHamaguchi, Hiro-oen_US
dc.contributor.authorIwata, Koichien_US
dc.contributor.department應用化學系分子科學碩博班zh_TW
dc.contributor.departmentInstitute of Molecular scienceen_US
dc.date.accessioned2014-12-08T15:23:35Z
dc.date.available2014-12-08T15:23:35Z
dc.date.issued2012-06-05en_US
dc.description.abstractNanosecond time-resolved infrared spectra of photoexcited 9,9'-bianthryl (BA) and its deuterated derivative (BA-d(18)) were recorded in acetonitrile-d(3) and cyclohexane-d(12). The charge-transfer (CT) bands observed at the 1200-1400 cm(-1) region are contributed mostly by the intra- and inter-ring CC stretch vibrations. The intrinsic frequency of the inter-ring CC stretch falls within the 1200-1400 cm(-1) region, which is consistent more with a twisted structure than with a fully conjugated planar structure of the CT state.en_US
dc.identifier.issn0366-7022en_US
dc.identifier.journalCHEMISTRY LETTERSen_US
dc.identifier.urihttps://ir.lib.nycu.edu.tw/handle/11536/16490
dc.identifier.wosnumberWOS:000305918400033
dc.language.isoen_USen_US
dc.titleNanosecond Time-resolved Infrared Spectra and Structure of the Charge-transfer State of 9,9 '-Bianthryl in Acetonitrileen_US
dc.typeArticleen_US

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