Preparations, thermal properties, and T-g increase mechanism of inorganic/organic hybrid polymers based on polyhedral oligomeric silsesquioxanes
| dc.citation.epage | 8793 | en_US |
| dc.citation.issue | 23 | en_US |
| dc.citation.spage | 8788 | en_US |
| dc.citation.volume | 35 | en_US |
| dc.citation.woscount | 230 | |
| dc.contributor.author | Xu, HY | en_US |
| dc.contributor.author | Kuo, SW | en_US |
| dc.contributor.author | Lee, JS | en_US |
| dc.contributor.author | Chang, FC | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:41:45Z | |
| dc.date.available | 2014-12-08T15:41:45Z | |
| dc.date.issued | 2002-11-05 | en_US |
| dc.description.abstract | A series of novel hybrid poly(acetoxylstyrene-co-isobutylstyryl-POSS)s (PAS-POSS) and poly(vinylpyrrolidone-co-isobutylstyryl-POSS)s (PVP-POSS) are synthesized and characterized. The POSS content in these hybrids can be controlled by varying the monomer feed ratio. The polyhedral oligosilsesquoixane (POSS) moiety can effectively increase the T-g of the resultant organic/inorganic hybrid polymer at a relatively high POSS content and produce the hybrid copolymer with narrower molecular weight distribution. The FTIR spectra are used to investigate the structure-property relationship of these hybrid polymers, and the T-g enhancement mechanism is discussed in detail. | en_US |
| dc.identifier.doi | 10.1021/ma0202843 | en_US |
| dc.identifier.issn | 0024-9297 | en_US |
| dc.identifier.journal | MACROMOLECULES | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1021/ma0202843 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/28389 | |
| dc.identifier.wosnumber | WOS:000178954100024 | |
| dc.language.iso | en_US | en_US |
| dc.title | Preparations, thermal properties, and T-g increase mechanism of inorganic/organic hybrid polymers based on polyhedral oligomeric silsesquioxanes | en_US |
| dc.type | Article | en_US |