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Physical aging of cyclo olefin copolymer (COC)

dc.citation.epage200en_US
dc.citation.issue3en_US
dc.citation.spage195en_US
dc.citation.volume10en_US
dc.citation.woscount5
dc.contributor.authorHuang, WJen_US
dc.contributor.authorChang, FCen_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.date.accessioned2014-12-08T15:41:33Z
dc.date.available2014-12-08T15:41:33Z
dc.date.issued2003en_US
dc.description.abstractThe physical aging behaviour of the cyclo olefin copolymer (COC) has been investigated in this paper by using low temperature annealing in differential scanning calorimeter (DSC) measurements. The data of recovered enthalpies was fitted by means of Petrie-Marshall (PM), Cowie-Ferguson (CF) or Kohlrausch-Williams-Watts (KWW) form equation in describing the enthalpy relaxation. We have found that the COC sample has a stretched exponential factor near 1.0 (beta = 0.98 +/- 0.02) at the annealing temperature range. The apparent activation energy (EH) of COC aging obtained by using the Petrie/Marshall (PM) analysis method is about 1521.7 +/- 150 kJ/mole. That is substantially higher than 308 50 kJ/mole for bisphenol-A polycarbonate, 407.4 kJ/mole for poly (vinyl methyl ether) and 1192 kJ/mole for polystyrene, but close to 1520 kJ/mole for polyterafluoroethylene (PTFE).en_US
dc.identifier.doi10.1023/A:1026088308671en_US
dc.identifier.issn1022-9760en_US
dc.identifier.journalJOURNAL OF POLYMER RESEARCH-TAIWANen_US
dc.identifier.urihttp://dx.doi.org/10.1023/A:1026088308671en_US
dc.identifier.urihttps://ir.lib.nycu.edu.tw/handle/11536/28259
dc.identifier.wosnumberWOS:000186610500006
dc.language.isoen_USen_US
dc.subjectactivation energyen_US
dc.subjectCOCen_US
dc.subjectphysical agingen_US
dc.titlePhysical aging of cyclo olefin copolymer (COC)en_US
dc.typeArticleen_US

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