A Theoretical Study on Radical-based Aminocarbonylation of Aryl Iodides

dc.citation.epage	1171	en_US
dc.citation.spage	1169	en_US
dc.citation.volume	47	en_US
dc.citation.woscount	1	en_US
dc.contributor.author	Kawamoto, Takuji	en_US
dc.contributor.author	Matsubara, Hiroshi	en_US
dc.contributor.author	Fukuyama, Takahide	en_US
dc.contributor.author	Ryu, Ilhyong	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.date.accessioned	2019-04-02T05:58:34Z
dc.date.available	2019-04-02T05:58:34Z
dc.date.issued	2018-09-01	en_US
dc.description.abstract	Aminocarbonylation of aromatic iodides with CO and amines gives aromatic amides under photoirradiation conditions. DFT calculations predict that methylamine adds to benzoyl radical to give a zwitterionic radical, which would afford the product via two pathways: (a) an amine-assisted proton transfer followed by a single electron transfer reaction (SET) with iodobenzene or (b) complexation with iodobenzene and then the SET.	en_US
dc.identifier.doi	10.1246/cl.180599	en_US
dc.identifier.issn	0366-7022	en_US
dc.identifier.journal	CHEMISTRY LETTERS	en_US
dc.identifier.uri	http://dx.doi.org/10.1246/cl.180599	en_US
dc.identifier.uri	https://ir.lib.nycu.edu.tw/handle/11536/148078
dc.identifier.wosnumber	WOS:000443399800009	en_US
dc.language.iso	en_US	en_US
dc.subject	DFT calculation	en_US
dc.subject	Radical aminocarbonylation	en_US
dc.subject	Single electron transfer	en_US
dc.title	A Theoretical Study on Radical-based Aminocarbonylation of Aryl Iodides	en_US
dc.type	Article	en_US

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