Radical Mediated Aza-Pauson-Khand Reaction of Acetylenes, Imines, and CO Leading to Five-Membered Unsaturated Lactams

dc.citation.epage	0	en_US
dc.citation.issue	10	en_US
dc.citation.spage	0	en_US
dc.citation.volume	102	en_US
dc.citation.woscount	0	en_US
dc.contributor.author	Fukuyama, Takahide	en_US
dc.contributor.author	Okada, Takuma	en_US
dc.contributor.author	Nakashima, Nao	en_US
dc.contributor.author	Ryu, Ilhyong	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.date.accessioned	2019-12-13T01:12:16Z
dc.date.available	2019-12-13T01:12:16Z
dc.date.issued	2019-10-01	en_US
dc.description.abstract	Formal [2+2+1] cycloaddition reaction involving acetylenes, aromatic imines, and CO was achieved by radical chain reaction, which gave five-membered unsaturated lactams in modest to good yields. When we used 5-chloropentyne, sequential carbonylation took place accompanied with double annulation events to give a cyclohexanone-fused lactam in excellent stereoselectivity.	en_US
dc.identifier.doi	10.1002/hlca.201900186	en_US
dc.identifier.issn	0018-019X	en_US
dc.identifier.journal	HELVETICA CHIMICA ACTA	en_US
dc.identifier.uri	http://dx.doi.org/10.1002/hlca.201900186	en_US
dc.identifier.uri	https://ir.lib.nycu.edu.tw/handle/11536/153144
dc.identifier.wosnumber	WOS:000496451400002	en_US
dc.language.iso	en_US	en_US
dc.subject	cycloaddition	en_US
dc.subject	alkynes	en_US
dc.subject	CO	en_US
dc.subject	aromatic imines	en_US
dc.subject	lactams	en_US
dc.title	Radical Mediated Aza-Pauson-Khand Reaction of Acetylenes, Imines, and CO Leading to Five-Membered Unsaturated Lactams	en_US
dc.type	Article	en_US

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