Fourier-transform microwave spectroscopy of dimethyl-substituted Criegee intermediate (CH3)(2)COO

dc.citation.issue	24	en_US
dc.citation.volume	145	en_US
dc.contributor.author	Nakajima, Masakazu	en_US
dc.contributor.author	Endo, Yasuki	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.date.accessioned	2017-04-21T06:56:41Z
dc.date.available	2017-04-21T06:56:41Z
dc.date.issued	2016-12-28	en_US
dc.description.abstract	Pure rotational transitions of the dimethyl-substituted Criegee intermediate (dimethyl carbonyl oxide, acetone oxide), (CH3)(2)COO, were observed in the discharge plasma of a C(CH3)(2)I-2/O-2 gas mixture by Fourier-transform microwave spectroscopy. The observed spectra show small splittings due to the internal rotations of the two methyl groups. Precise rotational constants of the molecule and the barrier heights of the methyl internal rotations were experimentally determined. Published by AIP Publishing.	en_US
dc.identifier.doi	10.1063/1.4973014	en_US
dc.identifier.issn	0021-9606	en_US
dc.identifier.journal	JOURNAL OF CHEMICAL PHYSICS	en_US
dc.identifier.uri	http://dx.doi.org/10.1063/1.4973014	en_US
dc.identifier.uri	https://ir.lib.nycu.edu.tw/handle/11536/133071
dc.identifier.wosnumber	WOS:000392174800024	en_US
dc.language.iso	en_US	en_US
dc.title	Fourier-transform microwave spectroscopy of dimethyl-substituted Criegee intermediate (CH3)(2)COO	en_US

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