Structural variations in the ternary system HfAl2-xCux (x=0.2-1.0)

Abstract

Synthesized ternary intermetallic phases HfAl2-xCux in a series with (x = 0.49, 0.88, 1.04) are characterized as Laves phase structures. X-ray diffraction revealed homogeneity within ranges 0.2 <= x <= 0.5 and 0.7 <= x <= 0.9 for structure types MgCu2 and MgNi2, respectively. When Cu atoms gradually replaced the Al atoms, the structure type altered in the sequence MgCu2 -> MgNi2 -> MgZn2, and the Kagome nets were distorted with varied bond lengths. Measurements of physical properties revealed these phases to be metallic, with resistances 4.35 (x = 0.5), 5.85 (x = 0.7), and 6.50 (x = 0.9) m Omega cm, respectively, at temperature 300 K. The coloring schemes reveal that, upon increasing the proportion of Cu atoms, the stability of these phases correlated with the arrangements of the Al and Cu atoms. Calculated electronic structures indicate that the bonding character is consistent with the experimentally observed phase width. (C) 2011 Elsevier Ltd. All rights reserved.