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Microscopic Origin of the Giant Ferroelectric Polarization in Tetragonal-like BiFeO3

dc.citation.epage0en_US
dc.citation.issue14en_US
dc.citation.spage0en_US
dc.citation.volume107en_US
dc.citation.woscount162en_US
dc.contributor.authorZhang, J. X.en_US
dc.contributor.authorHe, Q.en_US
dc.contributor.authorTrassin, M.en_US
dc.contributor.authorLuo, W.en_US
dc.contributor.authorYi, D.en_US
dc.contributor.authorRossell, M. D.en_US
dc.contributor.authorYu, P.en_US
dc.contributor.authorYou, L.en_US
dc.contributor.authorWang, C. H.en_US
dc.contributor.authorKuo, C. Y.en_US
dc.contributor.authorHeron, J. T.en_US
dc.contributor.authorHu, Z.en_US
dc.contributor.authorZeches, R. J.en_US
dc.contributor.authorLin, H. J.en_US
dc.contributor.authorTanaka, A.en_US
dc.contributor.authorChen, C. T.en_US
dc.contributor.authorTjeng, L. H.en_US
dc.contributor.authorChu, Y-H.en_US
dc.contributor.authorRamesh, R.en_US
dc.contributor.department材料科學與工程學系zh_TW
dc.contributor.departmentDepartment of Materials Science and Engineeringen_US
dc.date.accessioned2019-04-03T06:35:37Z
dc.date.available2019-04-03T06:35:37Z
dc.date.issued2011-09-29en_US
dc.description.abstractWe report direct experimental evidence for a room-temperature, similar to 130 mu C/cm(2) ferroelectric polarization from the tetragonal-like BiFeO3 phase. The physical origin of this remarkable enhancement of ferroelectric polarization has been investigated by a combination of x-ray absorption spectroscopy, scanning transmission electron microscopy, and first principles calculations. A large strain-induced Fe-ion displacement relative to the oxygen octahedra, combined with the contribution of Bi 6s lone pair electrons, is the mechanism driving the large ferroelectric polarization in this tetragonal-like phase.en_US
dc.identifier.doi10.1103/PhysRevLett.107.147602en_US
dc.identifier.issn0031-9007en_US
dc.identifier.journalPHYSICAL REVIEW LETTERSen_US
dc.identifier.urihttp://dx.doi.org/10.1103/PhysRevLett.107.147602en_US
dc.identifier.urihttps://ir.lib.nycu.edu.tw/handle/11536/150400
dc.identifier.wosnumberWOS:000296282800006en_US
dc.language.isoen_USen_US
dc.titleMicroscopic Origin of the Giant Ferroelectric Polarization in Tetragonal-like BiFeO3en_US
dc.typeArticleen_US

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