Electrochemiluminescence studies of the cyclometalated iridium(III) complexes with substituted 2-phenylbenzothiazole ligands
| dc.citation.epage | 831 | en_US |
| dc.citation.issue | 8 | en_US |
| dc.citation.spage | 827 | en_US |
| dc.citation.volume | 6 | en_US |
| dc.citation.woscount | 38 | |
| dc.contributor.author | Kapturkiewicz, A | en_US |
| dc.contributor.author | Chen, TM | en_US |
| dc.contributor.author | Laskar, IR | en_US |
| dc.contributor.author | Nowacki, J | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:38:44Z | |
| dc.date.available | 2014-12-08T15:38:44Z | |
| dc.date.issued | 2004-08-01 | en_US |
| dc.description.abstract | Electrogenerated chemiluminescence (ECL) studies have been performed for the iridium(III) cyclometalated L2Ir(acac) complexes with substituted 2-phenylbenzothiazole ligand L. Electron transfer (ET) generation of the excited (3)*L2Ir(acac) has been studied using a triple-potential-step technique in acetonitrile-dioxane (1:1) solutions containing 0.1 M (n-C4H9)(4)NPF6 as the supporting electrolyte. ET reactions between electrochemically generated L2Ir(acac)(+) and A(-) (radical anions of aromatic nitriles) species lead to very efficient generation of ECL emission. Extremely high ECL efficiencies (up to 0.40) close to the excited (3)*L2Ir(acac) luminescence yields have been found. (C) 2004 Elsevier B.V. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.elecom.2004.06.006 | en_US |
| dc.identifier.issn | 1388-2481 | en_US |
| dc.identifier.journal | ELECTROCHEMISTRY COMMUNICATIONS | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1016/j.elecom.2004.06.006 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/26500 | |
| dc.identifier.wosnumber | WOS:000222894600017 | |
| dc.language.iso | en_US | en_US |
| dc.subject | electrogenerated chemiluminescence | en_US |
| dc.subject | iridium complexes | en_US |
| dc.subject | MLCT excited state | en_US |
| dc.title | Electrochemiluminescence studies of the cyclometalated iridium(III) complexes with substituted 2-phenylbenzothiazole ligands | en_US |
| dc.type | Article | en_US |