Oxidation of 3-furfurylcarbinois with bromine in acetone-water

dc.citation.epage	238	en_US
dc.citation.issue	1	en_US
dc.citation.spage	233	en_US
dc.citation.volume	55	en_US
dc.citation.woscount	3
dc.contributor.author	Harn, Piin-Jye	en_US
dc.contributor.author	Lin, Chu-Chung	en_US
dc.contributor.author	Wu, Hsien-Jen	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.date.accessioned	2014-12-08T15:12:37Z
dc.date.available	2014-12-08T15:12:37Z
dc.date.issued	2008-02-01	en_US
dc.description.abstract	Oxidation of 3-furfurylcarbinols 3a-e and 7 with bromine in acetone-water solution gave the 2-substituted-3-furfurals 4a-e and 8 in good yields, respectively. Reaction of 2-alkyl-3-furfurylcarbinols 9a and 9b with bromine in acetone-water gave the bromoalkyl 3-furfuryl ketones 10a and 10b as the major products. A reaction mechanism via the cis-trans isomerization of the 2-ene-1,4-diones 13 and 14 was proposed to account for the transposition of the alkyl group of the 3-furfurylcarbinols 3, 7 and 9 to the 2-position on the furan ring of the products 4, 8 and 10.	en_US
dc.identifier.issn	0009-4536	en_US
dc.identifier.journal	JOURNAL OF THE CHINESE CHEMICAL SOCIETY	en_US
dc.identifier.uri	https://ir.lib.nycu.edu.tw/handle/11536/9695
dc.identifier.wosnumber	WOS:000258937200035
dc.language.iso	en_US	en_US
dc.subject	3-furfurylcarbinols	en_US
dc.subject	oxidation with bromine	en_US
dc.title	Oxidation of 3-furfurylcarbinois with bromine in acetone-water	en_US
dc.type	Article	en_US

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