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Highly selective fluorescent sensors for mercury(II) ions and their applications in living cell imaging

dc.citation.epage1969en_US
dc.citation.issue8en_US
dc.citation.spage1965en_US
dc.citation.volume69en_US
dc.citation.woscount13
dc.contributor.authorWang, Hsuan-Fuen_US
dc.contributor.authorWu, Shu-Paoen_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.date.accessioned2014-12-08T15:29:27Z
dc.date.available2014-12-08T15:29:27Z
dc.date.issued2013-02-25en_US
dc.description.abstractThree new pyrene derivatives (MS1, MS2, and MS3) containing two triazole units exhibited fluorescence quenching in the presence of Hg2+ ions. Other metal ions Ag+, Ca2+, Cd2+,Co2+, Cu2+, Fe2+, Fe3+, K+, Mg2+, Mn2+, Na+, Ni2+, Pb2+, Rb+, and Zn2+ produced only minor changes in the fluorescence of MS1, MS2, and MS3. The binding ratio of the chemosensor-Hg2+ complexes was found to be 1:1 according to Job plot experiments. The association constants (K-a) of chemosensor-Hg2+ complexes were found to be 1.68x10(3) M-1 (MS1), 1.57x10(3) M-1 (MS2), and 1.52x10(3) M-1 (MS3), respectively. Moreover, fluorescence microscopy experiments showed that MS1 could be used as a fluorescent probe for detecting Hg2+ in living cells. (C) 2013 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.tet.2012.12.075en_US
dc.identifier.issn0040-4020en_US
dc.identifier.journalTETRAHEDRONen_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.tet.2012.12.075en_US
dc.identifier.urihttps://ir.lib.nycu.edu.tw/handle/11536/21203
dc.identifier.wosnumberWOS:000315062800001
dc.language.isoen_USen_US
dc.subjectSensorsen_US
dc.subjectMercury(II)en_US
dc.subjectPyreneen_US
dc.subjectImaging agentsen_US
dc.titleHighly selective fluorescent sensors for mercury(II) ions and their applications in living cell imagingen_US
dc.typeArticleen_US

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