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dc.contributor.authorTsai, Yi-Chouen_US
dc.contributor.authorLu, Duan-Yenen_US
dc.contributor.authorLin, Yang-Miinen_US
dc.contributor.authorHwang, Jenn-Kangen_US
dc.contributor.authorYu, Jen-Shiang K.en_US
dc.date.accessioned2014-12-08T15:15:07Z-
dc.date.available2014-12-08T15:15:07Z-
dc.date.issued2007en_US
dc.identifier.issn1359-7345en_US
dc.identifier.urihttp://hdl.handle.net/11536/11364-
dc.identifier.urihttp://dx.doi.org/10.1039/b707396hen_US
dc.description.abstractReduction of Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2) with 4 equiv. of KC8 resulted in a dramatic structural transformation into [(eta(2)- Me2Si( NDipp)(2)) ZnZn(eta(2)- Me2Si( NDipp)(2))](2-) featuring a Zn - Zn bond instead of [Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2)](2-); the mechanism of the observed structural transformations arising from the Zn - Zn bond formation involving the intermediate of [Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2)](-) was elucidated by elaborate computations.en_US
dc.language.isoen_USen_US
dc.titleStructural transformations in dinuclear zinc complexes involving Zn-Zn bondsen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/b707396hen_US
dc.identifier.journalCHEMICAL COMMUNICATIONSen_US
dc.citation.issue40en_US
dc.citation.spage4125en_US
dc.citation.epage4127en_US
dc.contributor.department生物科技學系zh_TW
dc.contributor.departmentDepartment of Biological Science and Technologyen_US
dc.identifier.wosnumberWOS:000250085500013-
dc.citation.woscount46-
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