A study of monomer's effect on adhesion strength of UV-curable resins

Abstract

This work studies the effects of the monomer types, the number of hydroxyl functional groups (-OH) on polyol monomers, and the equivalent weight ratio of dicycloaliphatic epoxide to polyol for cationic polymerization (the R value) on the adhesion strength of UV-curable epoxy resins applied to organic light-emitting device (OLED) packaging. It was found that the volume shrinkage of resins after UV curing is related to the crosslinking density of the resin. The smallest volume shrinkage implied the highest adhesion strength of resin on glass substrate since the internal stress was minimized. This study observed that the resin containing polyol monomer is able to achieve the smallest degree of shrinkage (1.72%) and the highest adhesion strength (153.35 kg/cm(2)) on glass substrate. (C) 2005 Elsevier Ltd. All rights reserved.