完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Yao, I-Chun | en_US |
dc.contributor.author | Cheng, Ming-Hsiang | en_US |
dc.contributor.author | Chen, Jiun-Tai | en_US |
dc.date.accessioned | 2016-03-28T00:04:21Z | - |
dc.date.available | 2016-03-28T00:04:21Z | - |
dc.date.issued | 2015-11-01 | en_US |
dc.identifier.issn | 1022-1352 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1002/macp.201500264 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/129586 | - |
dc.description.abstract | Block copolymer micelles are generally formed by the self-assembly of amphiphilic copolymer molecules in aqueous medium. Although different types of block copolymer micelles have been studied, the self-assembly behavior of block copolymer micelles in confined geometries have been rarely studied. In this work, the fabrication of polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) micelle nanotubes in the cylindrical nanopores of anodic aluminum oxide templates using a solvent-annealing-assisted wetting method is presented. The PS-b-P4VP chains wet the pore walls in the form of micelles when the sample is annealed in the vapor of toluene, a good solvent for PS and a nonsolvent for P4VP. The formation of the PS-b-P4VP micelle nanotubes instead of nanorods implies that the micelles wet the nanopores in the complete wetting regime. This study not only contributes to a deeper understanding of the self-assembly behavior of block polymer micelles in confined geometries, but also provides more possible variations and design freedoms in the application of block copolymer micelles. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | anodic aluminum oxide (AAO) | en_US |
dc.subject | block copolymers | en_US |
dc.subject | micelles | en_US |
dc.subject | nanotubes | en_US |
dc.subject | solvent annealing | en_US |
dc.title | Block Copolymer Micelle Nanotubes by the Solvent-Annealing-Induced Nanowetting in Anodic Aluminum Oxide Templates | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1002/macp.201500264 | en_US |
dc.identifier.journal | MACROMOLECULAR CHEMISTRY AND PHYSICS | en_US |
dc.citation.volume | 216 | en_US |
dc.citation.issue | 22 | en_US |
dc.citation.spage | 2154 | en_US |
dc.citation.epage | 2160 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000366391100001 | en_US |
dc.citation.woscount | 0 | en_US |
顯示於類別: | 期刊論文 |