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dc.contributor.authorLin, CCen_US
dc.contributor.authorHuang, FJen_US
dc.contributor.authorLin, JCen_US
dc.contributor.authorWu, HJen_US
dc.date.accessioned2014-12-08T15:02:44Z-
dc.date.available2014-12-08T15:02:44Z-
dc.date.issued1996-04-01en_US
dc.identifier.issn0009-4536en_US
dc.identifier.urihttp://hdl.handle.net/11536/1359-
dc.description.abstractSeveral novel tetraacetal oxa-cage compounds 9a-9f were synthesized from the corresponding 2-methylthiofurans 1a-1f by a short sequence. The structures of these tetraoxa-cage compounds were deduced from their spectral data and proven by X-ray analysis of 9a. Ozonolysis of the endo adducts 5a-5f in CH2Cl2 at -78 degrees C followed by reduction with dimethyl sulfide gave the tetraoxa-cages 9a-9f in 65-75% yields, respectively. Ozonolysis of the exo adduct 6a under the same reaction conditions gave the tetracarbonyl compound 10. The phenylthio group substituted tetraoxa-cage 13 and the tetraacetal oxa-cage 17, with one more carbon atom on the apex position, were also synthesized in a similar sequence.en_US
dc.language.isoen_USen_US
dc.titleSynthesis of novel tetraacetal oxa-cage compounds from 2-methylthiofuransen_US
dc.typeArticleen_US
dc.identifier.journalJOURNAL OF THE CHINESE CHEMICAL SOCIETYen_US
dc.citation.volume43en_US
dc.citation.issue2en_US
dc.citation.spage177en_US
dc.citation.epage186en_US
dc.contributor.department交大名義發表zh_TW
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentNational Chiao Tung Universityen_US
dc.contributor.departmentDepartment of Applied Chemistryen_US
Appears in Collections:Articles