A Hydrogen Pyrophosphate Selective Anion Receptor Based on Thiosemicarbazone

doi:10.1002/bkcs.11320

標題:	A Hydrogen Pyrophosphate Selective Anion Receptor Based on Thiosemicarbazone
作者:	Pandian, Thiravidamani Senthil Srinivasadesikan, Venkatesan Lin, Ming-Chang Park, Jong I. L. Kang, Jongmin 應用化學系 Department of Applied Chemistry
關鍵字:	Anion receptor;Hydrogen bonding;Hydrogen pyrophosphate;Thiourea
公開日期:	1-Dec-2017
摘要:	A novel rigid anion receptor 1 containing thiosemicarbazone groups were synthesized. Receptor 1 displayed competitive turn-off fluorescence and colorimetric response for hydrogen pyrophosphate. This recognition process was confirmed by UV-vis, fluorescence titrations. A detailed analysis of the TD-density functional theory calculations was consistent with the observed colorimetric experiments. These experiments revealed that the colorimetric and fluorescent response is triggered by thiourea/ HP2O73- hydrogen bonding.
URI:	http://dx.doi.org/10.1002/bkcs.11320 http://hdl.handle.net/11536/144235
ISSN:	1229-5949
DOI:	10.1002/bkcs.11320
期刊:	BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume:	38
起始頁:	1435
結束頁:	1442
Appears in Collections:	Articles