標題: Palladium/Light Induced Radical Alkenylation and Allylation of Alkyl Iodides Using Alkenyl and Allylic Sulfones
作者: Sumino, Shuhei
Uno, Misae
Huang, Hsin-Ju
Wu, Yen-Ku
Ryu, Ilhyong
應用化學系
Department of Applied Chemistry
公開日期: 16-Feb-2018
摘要: Alkenylation and allylation of alkyl iodides with alkenyl and allyl sulfones, respectively, took place under Pd/photoirradiation system. The initial alkyl radical, derived from a single electron transfer between Pd(0) and RI, underwent the title transformations. Pd(0) was regenerated through a reductive elimination of PhSO2PdI, which is formed by the combination of the sulfonyl radical and the palladium radical. The addition of water was effective, presumably by pushing the equilibrium through hydrolysis of PhSO2I.
URI: http://dx.doi.org/10.1021/acs.orglett.7b04050
http://hdl.handle.net/11536/144585
ISSN: 1523-7060
DOI: 10.1021/acs.orglett.7b04050
期刊: ORGANIC LETTERS
Volume: 20
起始頁: 1078
結束頁: 1081
Appears in Collections:Articles