A Combined Tamaru Allylation/Olefin Cross-Metathesis Approach for the Total Syntheses of (+/-)-Paniculidine B, (+/-)-Paniculidine C, and 2-Methylcarbazole

doi:10.1055/s-0036-1591739

標題:	A Combined Tamaru Allylation/Olefin Cross-Metathesis Approach for the Total Syntheses of (+/-)-Paniculidine B, (+/-)-Paniculidine C, and 2-Methylcarbazole
作者:	Tseng, Yi-Lun Liang, Min-Chieh Chen, I-Chia Wu, Yen-Ku 應用化學系 Department of Applied Chemistry
關鍵字:	prenylindoles;Tamaru allylation;cross-metathesis;carbazoles;total synthesis;alkaloids
公開日期:	1-Mar-2018
摘要:	A concise approach to the total syntheses of racemic paniculidines B and C is described. The route features a combined Tamaru allylation/olefin cross-metathesis sequence for the regiocontrolled synthesis of prenylindole intermediates. In addition, we report a transformation of the prenylated indole into 2-methylcarbazole catalyzed by sulfonic acid-functionalized silica gel.
URI:	http://dx.doi.org/10.1055/s-0036-1591739 http://hdl.handle.net/11536/144627
ISSN:	0936-5214
DOI:	10.1055/s-0036-1591739
期刊:	SYNLETT
Volume:	29
起始頁:	609
結束頁:	612
Appears in Collections:	Articles