Intercepting the Nazarov Oxyallyl Intermediate with -Formylvinyl Anion Equivalents to Access Formal Morita-Baylis-Hillman Alkylation Products

doi:10.1055/s-0036-1588769

完整後設資料紀錄

DC 欄位	值	語言
dc.contributor.author	Wu, Yen-Ku	en_US
dc.contributor.author	Lin, Rongrong	en_US
dc.contributor.author	West, F. G.	en_US
dc.date.accessioned	2018-08-21T05:54:18Z	-
dc.date.available	2018-08-21T05:54:18Z	-
dc.date.issued	2017-07-01	en_US
dc.identifier.issn	0936-5214	en_US
dc.identifier.uri	http://dx.doi.org/10.1055/s-0036-1588769	en_US
dc.identifier.uri	http://hdl.handle.net/11536/145789	-
dc.description.abstract	A Lewis acid catalyzed cationic domino reaction involving sequential electrocyclization and polar addition of allenol ethers onto the resulting oxyallyl species is described. The overall sequence allows a highly stereoselective synthesis of densely substituted cyclopentanoid compounds containing -formylvinyl functionality which is formally equivalent to products of a Morita-Baylis-Hillman alkylation process.	en_US
dc.language.iso	en_US	en_US
dc.subject	interrupted Nazarov cyclization	en_US
dc.subject	oxyallyl cation	en_US
dc.subject	allenol ethers	en_US
dc.subject	carbonyl umpolung	en_US
dc.subject	Morita-Baylis-Hillman alkylation	en_US
dc.title	Intercepting the Nazarov Oxyallyl Intermediate with -Formylvinyl Anion Equivalents to Access Formal Morita-Baylis-Hillman Alkylation Products	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1055/s-0036-1588769	en_US
dc.identifier.journal	SYNLETT	en_US
dc.citation.volume	28	en_US
dc.citation.spage	1486	en_US
dc.citation.epage	1490	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:000405534400019	en_US
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