標題: Direct infrared observation of hydrogen chloride anions in solid argon
作者: Huang, Tzu-Ping
Chen, Hui-Fen
Liu, Meng-Chen
Chin, Chih-Hao
Durrant, Marcus C.
Lee, Yin-Yu
Wu, Yu-Jong
應用化學系
Department of Applied Chemistry
公開日期: 21-Sep-2017
摘要: To facilitate direct spectroscopic observation of hydrogen chloride anions (HCl-), electron bombardment of CH3Cl diluted in excess Ar during matrix deposition was used to generate this anion. Subsequent characterization were performed by IR spectroscopy and quantum chemical calculations. Moreover the band intensity of HCl fi decays slowly when the matrix sample is maintained in the dark for a prolonged time. High-level ab inito calculation suggested that HCl fi is only weakly bound. Atom-in-molecule charge analysis indicated that both atoms of HCl fi are negatively charged and the Cl atom is hypervalent. Published by AIP Publishing.
URI: http://dx.doi.org/10.1063/1.4993638
http://hdl.handle.net/11536/146109
ISSN: 0021-9606
DOI: 10.1063/1.4993638
期刊: JOURNAL OF CHEMICAL PHYSICS
Volume: 147
Appears in Collections:Articles