Desymmetrization of 2,4,5,6-Tetra-O-benzyl-D-myo-inositol for the Synthesis of Mycothiol

標題:	Desymmetrization of 2,4,5,6-Tetra-O-benzyl-D-myo-inositol for the Synthesis of Mycothiol
作者:	Chung, Chuan-Chung Zulueta, Medel Manuel L. Padiyar, Laxmansingh T. Hung, Shang-Cheng 應用化學系 Department of Applied Chemistry
公開日期:	21-十月-2011
摘要:	An efficient chemical synthesis of mycothiol Involving the regioselective ketopinyl desymmetrization of 2,4,5,6-tetrabenzylated D-myo-inositol as the key step Is described. Together with a highly alpha-stereoselective D-glucosaminylation, the whole procedure was accomplished in eight steps with an overall yield of 40%.
URI:	http://dx.doi.org/10.1021/ol202218n http://hdl.handle.net/11536/14727
ISSN:	1523-7060
DOI:	10.1021/ol202218n
期刊:	ORGANIC LETTERS
Volume:	13
Issue:	20
起始頁:	5496
結束頁:	5499
顯示於類別：	期刊論文

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