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dc.contributor.authorChen, Yu-Chengen_US
dc.contributor.authorWen, Cheng-Cheen_US
dc.contributor.authorLiau, Ianen_US
dc.contributor.authorHsieh, You-Zungen_US
dc.contributor.authorHsu, Hsin-Yunen_US
dc.date.accessioned2019-04-02T06:01:04Z-
dc.date.available2019-04-02T06:01:04Z-
dc.date.issued2014-01-01en_US
dc.identifier.issn2050-750Xen_US
dc.identifier.urihttp://dx.doi.org/10.1039/c4tb00314den_US
dc.identifier.urihttp://hdl.handle.net/11536/147695-
dc.description.abstractA simple yet novel one-pot approach is developed to prepare carbon nanoparticles with diameters of similar to 2 nm and modified by oligonucleotides. We use single-stranded deoxyribonucleic acid (ssDNA), which serves as a unique 'bio-solvent' for carbon nanoparticle (CNP) preparation and as a target molecule for functionalisation. Proposed interactions relevant to the stabilisation of the final oligonucleotide-CNP complex include pi-pi stacking and pi-HN bonding with sp(2) carbon atoms on the CNP surface. Furthermore, oligonucleotide-enriched CNPs can be readily extracted within seconds from a crude mixture of single-walled carbon nanotubes (SWCNTs) without any need for post-synthesis chemical modification. The established CNPs are biocompatible, possess intrinsic fluorescence, and do not result in the undesirable photobleaching effect, rendering them potential candidates for in vivo biological applications.en_US
dc.language.isoen_USen_US
dc.titleOligonucleotides as 'bio-solvent' for in situ extraction and functionalisation of carbon nanoparticlesen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/c4tb00314den_US
dc.identifier.journalJOURNAL OF MATERIALS CHEMISTRY Ben_US
dc.citation.volume2en_US
dc.citation.spage4100en_US
dc.citation.epage4107en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.department應用化學系分子科學碩博班zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.contributor.departmentInstitute of Molecular scienceen_US
dc.identifier.wosnumberWOS:000337136000006en_US
dc.citation.woscount3en_US
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