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dc.contributor.authorChiang, Wei-Shenen_US
dc.contributor.authorHuang, Jun-Qianen_US
dc.contributor.authorTso, Kuang-Chihen_US
dc.contributor.authorHung, Pei-Sungen_US
dc.contributor.authorChen, Po-Chunen_US
dc.contributor.authorWu, Pu-Weien_US
dc.contributor.authorLee, Jyh-Fuen_US
dc.date.accessioned2019-04-02T05:58:50Z-
dc.date.available2019-04-02T05:58:50Z-
dc.date.issued2018-08-30en_US
dc.identifier.issn0040-6090en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.tsf.2018.05.020en_US
dc.identifier.urihttp://hdl.handle.net/11536/147981-
dc.description.abstractA composite Cu/MnOx thin film was fabricated by conducting electroplating of Cu and electrophoresis of MnOx colloids simultaneously in an organic electrolyte. The organic electrolyte was prepared by dissolving copper (II) acetylacetonate and manganese (II) acetylacetonate in ethylene glycol, with addition of 10 vol% acetic acid to improve ionic conductivity. Since both Cu ions and MnOx colloids carry positive charges, the formation of a composite film was achieved by a pulse current mode in which a low current pulse was used for Cu2+ reduction, followed by a high current pulse for the electrophoresis of the MnOx colloids. The Cu/MnOx composite film was dense and its X-ray diffraction pattern revealed a mixture of Cu, Mn2O3, and Mn3O4. Both X-ray photoelectron spectroscopy and X-ray absorption spectroscopy show consistent results confirming the metallic nature of Cu and oxidized state of Mn.en_US
dc.language.isoen_USen_US
dc.subjectCopperen_US
dc.subjectManganese oxideen_US
dc.subjectComposite filmen_US
dc.subjectElectrophoresisen_US
dc.subjectElectroplatingen_US
dc.subjectOrganic electrolyteen_US
dc.titleFormation of Cu/MnOx composite film by concurrent electroplating and electrophoresis in an organic solventen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.tsf.2018.05.020en_US
dc.identifier.journalTHIN SOLID FILMSen_US
dc.citation.volume660en_US
dc.citation.spage585en_US
dc.citation.epage589en_US
dc.contributor.department材料科學與工程學系zh_TW
dc.contributor.departmentDepartment of Materials Science and Engineeringen_US
dc.identifier.wosnumberWOS:000441177500078en_US
dc.citation.woscount0en_US
Appears in Collections:Articles