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dc.contributor.authorChin, Chih-Haoen_US
dc.contributor.authorLin, Meng-Yehen_US
dc.contributor.authorHuang, Tzu-Pingen_US
dc.contributor.authorWu, Pei-Zhenen_US
dc.contributor.authorWu, Yu-Jongen_US
dc.date.accessioned2019-04-02T06:00:25Z-
dc.date.available2019-04-02T06:00:25Z-
dc.date.issued2018-09-26en_US
dc.identifier.issn2045-2322en_US
dc.identifier.urihttp://dx.doi.org/10.1038/s41598-018-32644-3en_US
dc.identifier.urihttp://hdl.handle.net/11536/148212-
dc.description.abstractThe direct infrared (IR) absorption spectra of propargyl cations were recorded. These cations were generated via the electron bombardment of a propyne/Ar matrix sample during matrix deposition. Secondary photolysis with selected ultraviolet (UV) light was used for grouping the observed bands of various products. The band assignment of the propargyl cation in solid Ar was performed according by referring to the previous infrared photodissociation (IRPD) and velocity-map imaging photoelectron (VMI-PE) data, and via theoretical predictions of the anharmonic vibrational wavenumbers, band intensities, and deuterium-substituted isotopic ratios. Almost all the IR active bands with an observable intensity were recorded and the nu(11) mode was reported for the first time.en_US
dc.language.isoen_USen_US
dc.titleDirect IR Absorption Spectra of Propargyl Cation Isolated in Solid Argonen_US
dc.typeArticleen_US
dc.identifier.doi10.1038/s41598-018-32644-3en_US
dc.identifier.journalSCIENTIFIC REPORTSen_US
dc.citation.volume8en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000445615100021en_US
dc.citation.woscount0en_US
Appears in Collections:Articles