標題: Synthesis and characterization of heterocyclic conjugated polymers containing planar benzo[c]cinnoline and tetraazapyrene structures for organic field-effect transistor application
作者: Lee, Shih-Wei
Chien, Shih-Hsuan
Chen, Jyh-Chien
Wang, Shih-Hao
Wang, Lee-Yih
Lai, Bo-Han
Wang, Chien-Lung
應用化學系
Department of Applied Chemistry
關鍵字: Benzo[c]cinnoline;Traazapyrene;OFET;Heterocycli conjugated;Polymers;TVT
公開日期: 1-Mar-2019
摘要: Heterocyclic conjugated polymers BZCTVT and TAPTVT containing benzo[c]cinnoline (BZC) and tetraazapyrene (TAP), respectively, were prepared by using Stille coupling polymerization in microwave reactor. BZC and TAP act as acceptors and thiophene-vinylene-thiophene (TVT) acts as donors. Alkylated thiophene is the linker between acceptor and donor. This is the first time that tetraazapyrene was incorporated into conjugated polymers. The films of BZCTVT and TAPTVT showed maximum absorption wavelength at 522 and 534 nm, respectively. From cyclic voltammertry measurement, TAPTVT and BZCTVT exhibited low LUMO (-3.61 and -3.47 eV) and HOMO (-5.64 and -5.63 eV) energy levels. Even though BZC and TAP were planar structures, BZCTVT and TAPTVT showed large dihedral angles between alkylated thiophene and TVT (10.8-22.6 degrees), and between alkylated thiophene and BZC and TAP (22.2-30.3 degrees) based on their simulated energy-minimized geometry. The bottom-gate, top-contact OFETs based on TAPTVT and BZCTVT exhibited only p-channel behavior with hole mobility of 4.63 x 10(-4) and 1.04 x 10(-4) cm(2) V-1 s(-1) and current on/off ratios greater than 10(4) after thermal annealing. Grazing incidence X-ray diffraction (GIXRD) patterns suggested that thin films of TAPTVT and BZCTVT preferred edge-on orientation.
URI: http://dx.doi.org/10.1016/j.orgel.2018.12.027
http://hdl.handle.net/11536/148697
ISSN: 1566-1199
DOI: 10.1016/j.orgel.2018.12.027
期刊: ORGANIC ELECTRONICS
Volume: 66
起始頁: 136
結束頁: 147
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