標題: Synthesis and luminescence properties of Eu3+, Ce3+ and Tb3+-activated Sr3La2(BO3)(4) under UV excitation
作者: Kuo, Te-Wen
Chen, Teng-Ming
應用化學系
Department of Applied Chemistry
關鍵字: Phosphors;Sr3La2(BO3)(4):RE3+ (RE3+ = Eu3+, Ce3+, Tb3+);Luminescence
公開日期: 1-Mar-2010
摘要: The spectroscopic properties in UV-excitable range for the phosphors of Sr3La2(BO3)(4):RE3+ (RE3+ = Eu3+, Ce3+, Tb3+) were investigated. The phosphors were synthesized by conventional solid-state reactions. The photoluminescence (PL) spectra and commission international de l'Eclairage (CIE) coordinates of Sr3La2(BO3)4:RE 31 were investigated. The f-d transitions of Eu3+, Ce3+ and Tb3+ in the host lattices are assumed and corroborated. The PL and PL excitation (PLE) spectra indicate that the main emission wavelength of Sr3La2(BO3)(4):Eu3+ is 611 nm, and Sr3La2(BO3)(4):Ce3+ shows dominating emission peak at 425 nm, while Sr3La2(BO3)(4):Tb3+ displays green emission at 487, 542, 582 and 620 nm. These phosphors were prepared by simple solid-state reaction at 1000 degrees C. There are lower reactive temperature and more convenient than commercial phosphors. The Sr3La2(BO3)(4):Tb3+ applied to cold cathode fluorescent lamp was found to emit green light and have a major peak wavelength at around 542 nm. These phosphors may provide a new kind of luminescent materials under ultraviolet excitation. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.
URI: http://dx.doi.org/10.1016/j.jlumin.2009.10.018
http://hdl.handle.net/11536/149885
ISSN: 0022-2313
DOI: 10.1016/j.jlumin.2009.10.018
期刊: JOURNAL OF LUMINESCENCE
Volume: 130
起始頁: 483
結束頁: 487
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