Pure rotational spectrum of HCI

doi:10.1016/j.jms.2019.05.008

標題:	Pure rotational spectrum of HCI
作者:	Nakajima, Masakazu Endo, Yasuki 應用化學系 Department of Applied Chemistry
關鍵字:	Pure rotational transitions;HCI;Monohalomethylene;Monohalocarbene
公開日期:	1-Aug-2019
摘要:	The 1(01)-0(00) and 2(02)-1(01) rotational transitions of a monohalomethylene, HCI, are observed in a discharge plasma of diiodomethane by Fourier-transform microwave (FTMW) and FTMW-microwave double-resonance spectroscopy. The effective rotational constant (B + C)/2, the centrifugal distortion constant Delta(J), and the quadrupole coupling constant of the iodine nucleus are determined from the observed line frequencies. The nuclear spin-rotation coupling constant C-bb is required to be included into the set of fitting parameters for a satisfactory analysis of the observed line frequencies. (C) 2019 Elsevier Inc. All rights reserved.
URI:	http://dx.doi.org/10.1016/j.jms.2019.05.008 http://hdl.handle.net/11536/152691
ISSN:	0022-2852
DOI:	10.1016/j.jms.2019.05.008
期刊:	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume:	362
起始頁:	25
結束頁:	28
Appears in Collections:	Articles