標題: Formation of Halogen-bearing Species. II. Irradiation of Chloromethane in Carbon Monoxide Ice with VUV Light and Electrons
作者: Lin, Meng-Yeh
Huang, Tzu-Ping
Wu, Pei-Zhen
Chin, Chih-Hao
Wu, Yu-Jong
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
關鍵字: Astrochemistry;Molecular spectroscopy;Line positions;Molecule formation;Galaxy chemical evolution;Chemical abundances
公開日期: 1-一月-2020
摘要: The synthesis of chlorine-bearing species in CO ice was studied by the irradiation of CH3Cl:CO ice at 10 K with vacuum-ultraviolet (VUV) light and energetic electrons. In contrast to the photochemical behavior of CH3F:CO ice, photolysis of CH3Cl:CO ice with Ly alpha or broadband VUV light afforded various products. This discrepancy was attributed to the abundant absorption bands of CH3Cl in the VUV region, particularly in the Ly alpha region. The Cl-bearing species including Cl2O, ClCO, C3Cl2, C3HCl, and HOOCl were characterized by observing their IR features. In contrast, electron bombardment of ice mixtures produced various carbon oxides and primary products, such as CH2Cl and HCO. In addition, the mechanism of energetic processes in electron bombardment was discussed.
URI: http://dx.doi.org/10.3847/1538-4357/ab5949
http://hdl.handle.net/11536/153494
ISSN: 0004-637X
DOI: 10.3847/1538-4357/ab5949
期刊: ASTROPHYSICAL JOURNAL
Volume: 888
Issue: 1
起始頁: 0
結束頁: 0
顯示於類別:期刊論文