完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Chang, Wei-Chieh | en_US |
dc.contributor.author | Raj, Ankit | en_US |
dc.contributor.author | Hiramatsu, Hirotsugu | en_US |
dc.contributor.author | Li, Han-Jung | en_US |
dc.contributor.author | Ziegler, Micah S. | en_US |
dc.contributor.author | Lin, Yichen | en_US |
dc.contributor.author | Huang, Shengcih | en_US |
dc.contributor.author | Liu, Hsueh-Ju | en_US |
dc.date.accessioned | 2020-10-05T01:59:40Z | - |
dc.date.available | 2020-10-05T01:59:40Z | - |
dc.date.issued | 2020-06-25 | en_US |
dc.identifier.issn | 1359-7345 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1039/d0cc02699a | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/154814 | - |
dc.description.abstract | A series of tri-tin complexes((LSn)-Sn-Ph)(3)Xwith triple-decker structures (L-Ph= 2,5-di(o-pyridyl)-3,4-diphenylpyrrolate; X = Cl, AlCl4, OTf, and PF6) was synthesized by reducingL(Ph)SnClwith (LiBBu3H)-Bu-s and subsequent reactions. Structural characterization of((LSn)-Sn-Ph)(3)Clrevealed a Sn-Sn-Sn core, and DFT calculations suggest that its HOMO is primarily sigma-bonding along the tri-tin framework.((LSn)-Sn-Ph)(3)Clreacts with W(CO)(5)THF to afford((LSn)-Sn-Ph)(2)(W(CO)(5))(2)andL(Ph)SnCl, implying that((LSn)-Sn-Ph)(3)Clmay exhibit dynamic behavior in solution. | en_US |
dc.language.iso | en_US | en_US |
dc.title | Linear, mixed-valent homocatenated tri-tin complexes featuring Sn-Sn bonds | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1039/d0cc02699a | en_US |
dc.identifier.journal | CHEMICAL COMMUNICATIONS | en_US |
dc.citation.volume | 56 | en_US |
dc.citation.issue | 50 | en_US |
dc.citation.spage | 6786 | en_US |
dc.citation.epage | 6789 | en_US |
dc.contributor.department | 交大名義發表 | zh_TW |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | 應用化學系分子科學碩博班 | zh_TW |
dc.contributor.department | National Chiao Tung University | en_US |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.contributor.department | Institute of Molecular science | en_US |
dc.identifier.wosnumber | WOS:000544928700006 | en_US |
dc.citation.woscount | 0 | en_US |
顯示於類別: | 期刊論文 |