完整後設資料紀錄
DC 欄位語言
dc.contributor.authorChang, Wei-Chiehen_US
dc.contributor.authorRaj, Ankiten_US
dc.contributor.authorHiramatsu, Hirotsuguen_US
dc.contributor.authorLi, Han-Jungen_US
dc.contributor.authorZiegler, Micah S.en_US
dc.contributor.authorLin, Yichenen_US
dc.contributor.authorHuang, Shengcihen_US
dc.contributor.authorLiu, Hsueh-Juen_US
dc.date.accessioned2020-10-05T01:59:40Z-
dc.date.available2020-10-05T01:59:40Z-
dc.date.issued2020-06-25en_US
dc.identifier.issn1359-7345en_US
dc.identifier.urihttp://dx.doi.org/10.1039/d0cc02699aen_US
dc.identifier.urihttp://hdl.handle.net/11536/154814-
dc.description.abstractA series of tri-tin complexes((LSn)-Sn-Ph)(3)Xwith triple-decker structures (L-Ph= 2,5-di(o-pyridyl)-3,4-diphenylpyrrolate; X = Cl, AlCl4, OTf, and PF6) was synthesized by reducingL(Ph)SnClwith (LiBBu3H)-Bu-s and subsequent reactions. Structural characterization of((LSn)-Sn-Ph)(3)Clrevealed a Sn-Sn-Sn core, and DFT calculations suggest that its HOMO is primarily sigma-bonding along the tri-tin framework.((LSn)-Sn-Ph)(3)Clreacts with W(CO)(5)THF to afford((LSn)-Sn-Ph)(2)(W(CO)(5))(2)andL(Ph)SnCl, implying that((LSn)-Sn-Ph)(3)Clmay exhibit dynamic behavior in solution.en_US
dc.language.isoen_USen_US
dc.titleLinear, mixed-valent homocatenated tri-tin complexes featuring Sn-Sn bondsen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/d0cc02699aen_US
dc.identifier.journalCHEMICAL COMMUNICATIONSen_US
dc.citation.volume56en_US
dc.citation.issue50en_US
dc.citation.spage6786en_US
dc.citation.epage6789en_US
dc.contributor.department交大名義發表zh_TW
dc.contributor.department應用化學系zh_TW
dc.contributor.department應用化學系分子科學碩博班zh_TW
dc.contributor.departmentNational Chiao Tung Universityen_US
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.contributor.departmentInstitute of Molecular scienceen_US
dc.identifier.wosnumberWOS:000544928700006en_US
dc.citation.woscount0en_US
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