完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | JUANG, DY | en_US |
dc.contributor.author | LEE, JS | en_US |
dc.contributor.author | WANG, NS | en_US |
dc.date.accessioned | 2014-12-08T15:03:05Z | - |
dc.date.available | 2014-12-08T15:03:05Z | - |
dc.date.issued | 1995-11-01 | en_US |
dc.identifier.issn | 0538-8066 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1002/kin.550271108 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/1673 | - |
dc.description.abstract | The rate coefficients of the reactions of NCO radicals with NO and NO2: (1) NCO + NO --> products (293-836 K) and : (2) NCO + NO2 --> products (294-774 K) were measured by means of laser photolysis and-laser induced fluorescence technique in the indicated temperature ranges. NCO radicals were produced from the reaction of CN, from photodissociation of ICN or BrCN, with O-2. The concentration of NCO was monitored with a dye laser set at 414.95 nm. We determined k(1) = 1.73 x 10(-5) T--2.01 exp(-470/T) cm(3) molecule(-1) s(-1) that agrees with published results at room temperature and confirms the temperature dependence of an early report. A non-Arrhenius negative temperature dependence of k(2) was observed in-this work that agrees satisfactorily with results for a shock tube(18) near 1250 K. We obtained k(2) = 6.4 x 10(-10) T--0.646 exp(164/T) cm(3) molecule(-1) s(-1) for 1250 K greater than or equal to T greater than or equal to 294 K by combining data of these two measurements. Our result at 294 K and the temperature dependence disagree with results of two previous investigations. (C) 1995 John Wiley & Sons, Inc. | en_US |
dc.language.iso | en_US | en_US |
dc.title | KINETICS OF THE REACTIONS OF NCO WITH NO AND NO2 | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1002/kin.550271108 | en_US |
dc.identifier.journal | INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | en_US |
dc.citation.volume | 27 | en_US |
dc.citation.issue | 11 | en_US |
dc.citation.spage | 1111 | en_US |
dc.citation.epage | 1120 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:A1995TB25000007 | - |
dc.citation.woscount | 26 | - |
顯示於類別: | 期刊論文 |