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dc.contributor.authorJUANG, DYen_US
dc.contributor.authorLEE, JSen_US
dc.contributor.authorWANG, NSen_US
dc.date.accessioned2014-12-08T15:03:05Z-
dc.date.available2014-12-08T15:03:05Z-
dc.date.issued1995-11-01en_US
dc.identifier.issn0538-8066en_US
dc.identifier.urihttp://dx.doi.org/10.1002/kin.550271108en_US
dc.identifier.urihttp://hdl.handle.net/11536/1673-
dc.description.abstractThe rate coefficients of the reactions of NCO radicals with NO and NO2: (1) NCO + NO --> products (293-836 K) and : (2) NCO + NO2 --> products (294-774 K) were measured by means of laser photolysis and-laser induced fluorescence technique in the indicated temperature ranges. NCO radicals were produced from the reaction of CN, from photodissociation of ICN or BrCN, with O-2. The concentration of NCO was monitored with a dye laser set at 414.95 nm. We determined k(1) = 1.73 x 10(-5) T--2.01 exp(-470/T) cm(3) molecule(-1) s(-1) that agrees with published results at room temperature and confirms the temperature dependence of an early report. A non-Arrhenius negative temperature dependence of k(2) was observed in-this work that agrees satisfactorily with results for a shock tube(18) near 1250 K. We obtained k(2) = 6.4 x 10(-10) T--0.646 exp(164/T) cm(3) molecule(-1) s(-1) for 1250 K greater than or equal to T greater than or equal to 294 K by combining data of these two measurements. Our result at 294 K and the temperature dependence disagree with results of two previous investigations. (C) 1995 John Wiley & Sons, Inc.en_US
dc.language.isoen_USen_US
dc.titleKINETICS OF THE REACTIONS OF NCO WITH NO AND NO2en_US
dc.typeArticleen_US
dc.identifier.doi10.1002/kin.550271108en_US
dc.identifier.journalINTERNATIONAL JOURNAL OF CHEMICAL KINETICSen_US
dc.citation.volume27en_US
dc.citation.issue11en_US
dc.citation.spage1111en_US
dc.citation.epage1120en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:A1995TB25000007-
dc.citation.woscount26-
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