完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Hsu, Hsin-Ling | en_US |
dc.contributor.author | Tien, Cheng-Fang | en_US |
dc.contributor.author | Yang, Ya-Ting | en_US |
dc.contributor.author | Leu, Jihperng | en_US |
dc.date.accessioned | 2014-12-08T15:29:53Z | - |
dc.date.available | 2014-12-08T15:29:53Z | - |
dc.date.issued | 2013-02-28 | en_US |
dc.identifier.issn | 0013-4686 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1016/j.electacta.2012.12.133 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/21424 | - |
dc.description.abstract | Novel agarose gel electrolytes are prepared by allylimidazolium iodides-based ionic liquids and environmentally benign co-solvents (propylene carbonate (PC) and dimethyl sulfoxide (DMSO)) for dye-sensitized solar cells (DSSCs). Among 1-allyl-3-ethylimidadolium iodide (AEII), 1-allyl-3-propylimidazolium iodide (APII), 1-3-diallylimidazolium iodide (DAM, and 1-methyl-3-propylimidazolium iodide (MPII) ionic liquids, the agarose gel electrolyte containing AEII exhibits the best DSSC performance. The efficiency of the DSSC using the agarose gel electrolyte containing 1.5 M AEII and 0.65 wt% agarose is 5.89% with the highest I-3(-) diffusion coefficient of 7.7 x 10(-6) cm(2) s(-1). The performance of the AEII ionic liquid-based agarose gel electrolyte is comparable to the liquid electrolyte based on 3-methoxypropionitrile (MPN) (5.84%) under illumination at AM 1.5, 100 mW cm(-2). Moreover, the DSSC performance of the allylimidazolium iodides ionic liquid-based agarose electrolyte is determined by the interaction between ionic liquid and agarose, which affects the rigidity of the ion channels and the I-3(-) diffusion coefficient. (C) 2013 Elsevier Ltd. All rights reserved. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | Allylimidazolium iodides | en_US |
dc.subject | Ionic liquids | en_US |
dc.subject | Agarose gel electrolyte | en_US |
dc.subject | Dye-sensitized solar cell | en_US |
dc.subject | Environmentally benign solvents | en_US |
dc.title | Dye-sensitized solar cells based on agarose gel electrolytes using allylimidazolium iodides and environmentally benign solvents | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1016/j.electacta.2012.12.133 | en_US |
dc.identifier.journal | ELECTROCHIMICA ACTA | en_US |
dc.citation.volume | 91 | en_US |
dc.citation.issue | en_US | |
dc.citation.spage | 208 | en_US |
dc.citation.epage | 213 | en_US |
dc.contributor.department | 材料科學與工程學系 | zh_TW |
dc.contributor.department | Department of Materials Science and Engineering | en_US |
dc.identifier.wosnumber | WOS:000316707400029 | - |
dc.citation.woscount | 6 | - |
顯示於類別: | 期刊論文 |