1-(3-Methoxycarbonyl)propyl-2-selenyl-[6,6]-methanofullerene as a n-Type Material for Organic Solar Cells

Abstract

Demand for green and renewable energy is stimulating research into future materials for energy production. Thin films of materials possessing both electron accepting and donating functions play a unique role in solar energy technology because of their lightweight, flexibility, and economical, low-temperature, and large-area fabrication. A [60]fullerene derivative,[6,6]-2-selenyl-C(61)-butyric acid methyl ester (SeCBM), has been synthesized in three steps, namely through Friedel-Crafts acylation of selenophene, hydrazone formation and Bamford-Steven reaction. Organic photovoltaic device incorporating SeCBM and the conducting polymer P3HT exhibited an average power conversion efficiency of 3.26% and a champion efficiency as high as 3.81% under AM 1.5G irradiation. (C) 2011 Elsevier B.V. All rights reserved.