Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cheng, Chih-Chia | en_US |
dc.contributor.author | Yen, Ying-Chieh | en_US |
dc.contributor.author | Chang, Feng-Chih | en_US |
dc.date.accessioned | 2014-12-08T15:31:54Z | - |
dc.date.available | 2014-12-08T15:31:54Z | - |
dc.date.issued | 2011-06-16 | en_US |
dc.identifier.issn | 1022-1336 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1002/marc.201100167 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/22540 | - |
dc.description.abstract | A new polyhedral oligomeric silsesquioxane macromer, octakis[N-(6-aminopyridin-2-yl)-undecanamide-10-dimethyl-siloxy]silsesquioxane (POSS-C11-Py), containing eight diaminopyridine arms, is able to self-assemble to form a physically crosslinked polymer-like structure with good mechanical properties (tensile strength = 46.1 MPa, tensile modulus = 0.58 GPa, elongation = 49.3%) through quadruple hydrogen bonding interactions between these arms. POSS-C11-Py is the first organic/inorganic supermolecule possessing polymer-like mechanical properties as a result of self-complementary interactions, providing a potential route toward the design and fabrication of polymer-like supramolecular materials. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | hydrogen bonding | en_US |
dc.subject | mechanical properties | en_US |
dc.subject | nanocomposites | en_US |
dc.subject | self-assembly | en_US |
dc.subject | supramolecular structures | en_US |
dc.title | Self-supporting Polymer from a POSS Derivative | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1002/marc.201100167 | en_US |
dc.identifier.journal | MACROMOLECULAR RAPID COMMUNICATIONS | en_US |
dc.citation.volume | 32 | en_US |
dc.citation.issue | 12 | en_US |
dc.citation.spage | 927 | en_US |
dc.citation.epage | 932 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000292477000012 | - |
dc.citation.woscount | 11 | - |
Appears in Collections: | Articles |
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