Tuning Reactivity of Glycosyl Imidinium Intermediate for 2-Azido-2-deoxyglycosyl Donors in alpha-Glycosidic Bond Formation

標題:	Tuning Reactivity of Glycosyl Imidinium Intermediate for 2-Azido-2-deoxyglycosyl Donors in alpha-Glycosidic Bond Formation
作者:	Ingle, Arun B. Chao, Chin-Sheng Hung, Wei-Cheng Mong, Kwok-Kong Tony 應用化學系 Department of Applied Chemistry
公開日期:	18-Oct-2013
摘要:	The chemical properties of nucleophile additives were investigated in a modulated glycosylation context. N-Formylmorpholine (NFM) was found to be an effective modulator for glycosylation with less reactive 2-azido-2-deoxythioglucosyl and thiogalactosyl donors.
URI:	http://dx.doi.org/10.1021/ol402519c http://hdl.handle.net/11536/22974
ISSN:	1523-7060
DOI:	10.1021/ol402519c
期刊:	ORGANIC LETTERS
Volume:	15
Issue:	20
起始頁:	5290
結束頁:	5293
Appears in Collections:	Articles

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