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dc.contributor.authorHsieh, Wen-Shuoen_US
dc.contributor.authorLin, Pangen_US
dc.contributor.authorWang, Sea-Fueen_US
dc.date.accessioned2014-12-08T15:36:56Z-
dc.date.available2014-12-08T15:36:56Z-
dc.date.issued2014-10-13en_US
dc.identifier.issn0360-3199en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.ijhydene.2014.08.060en_US
dc.identifier.urihttp://hdl.handle.net/11536/25332-
dc.description.abstractIn this study, a gadolinia-doped ceria (GDq-supported micro tubular SOFC (T-SOFC) was fabricated using extrusion and dip-coating techniques (Cell A). The effects of inserting a scandium-stabilized zirconia (ScSZ) layer as an electron blocking layer between the GDC layer and the GDC-Ni anode layer were also explored (Cell B). The microstructures and electrochemical performances of Cell A and Cell B were investigated and compared. The layer thicknesses of the GDC and ScSZ bi-layer electrolytes were approximately 285 mu m and 8 mu m respectively. With the inserted ScSZ layer, both the ohmic resistance and the polarization resistance significantly increased at all the operating temperatures. The increase in the ohmic resistance of Cell B was predominantly due to the interfacial resistance, while the substantial escalation in the polarization resistance was mainly because of the low bulk oxygen diffusion process in the ScSZ layer and the smaller charge transfer processes occurring at the interfaces. The OCV of Cell B showed a slight decrease from 1.06 to 0.98 V and that of Cell A experienced an obvious decline from 0.92 to 0.76 V as the temperature rose from 650 to 800 degrees C. The ScSZ layer of Cell B successfully inhibited the OCV loss caused by the electronic conduction in GDC. The maximum power densities (MPDs) of Cell A at 650, 700, 750, and 800 degrees C were 0.20, 0.27, 0.33, and 0.36 Wcm(-2), and those of Cell B 0.16, 0.23, 0.32, and 0.42 Wcm(-2). The MPD of Cell B was improved at temperatures above 750 degrees C but remained inferior to that of Cell A below 750 degrees C. This is due to the fact that, as operating temperature increased above 750 degrees C, the benefit of the higher OCV in Cell B surpassed the deficiency of the higher cell resistance, thereby leading to a higher MPD. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.en_US
dc.language.isoen_USen_US
dc.titleCharacteristics of electrolyte supported micro-tubular solid oxide fuel cells with GDC-ScSZ bilayer electrolyteen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.ijhydene.2014.08.060en_US
dc.identifier.journalINTERNATIONAL JOURNAL OF HYDROGEN ENERGYen_US
dc.citation.volume39en_US
dc.citation.issue30en_US
dc.citation.spage17267en_US
dc.citation.epage17274en_US
dc.contributor.department材料科學與工程學系zh_TW
dc.contributor.departmentDepartment of Materials Science and Engineeringen_US
dc.identifier.wosnumberWOS:000343839000049-
dc.citation.woscount2-
Appears in Collections:Articles