Synthesis of eburnamine, isoeburnamine, and eburnamonine via a spirocyclic intermediate

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DC Field	Value	Language
dc.contributor.author	Ho, TL	en_US
dc.contributor.author	Chen, CK	en_US
dc.date.accessioned	2014-12-08T15:37:06Z	-
dc.date.available	2014-12-08T15:37:06Z	-
dc.date.issued	2005	en_US
dc.identifier.issn	0018-019X	en_US
dc.identifier.uri	http://hdl.handle.net/11536/25464	-
dc.identifier.uri	http://dx.doi.org/10.1002/hlca.200590216	en_US
dc.description.abstract	Racemic eburnamonine (1) was synthesized via 6, an intermediate possessing local symmetry. Cleavage of the cyclopentene subunit led to pentacyclic aldehydes 8a/8b which on subsequent borohydride and Wolff-Kishner reductions gave 12. The final steps included a RuCl3-catalyzed periodate oxidation and pyridimum chlorochromate (PCC) oxidation. The penultimate intermediates were racemic eburnamine (2) and racemic isoeburnamine (3).	en_US
dc.language.iso	en_US	en_US
dc.title	Synthesis of eburnamine, isoeburnamine, and eburnamonine via a spirocyclic intermediate	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1002/hlca.200590216	en_US
dc.identifier.journal	HELVETICA CHIMICA ACTA	en_US
dc.citation.volume	88	en_US
dc.citation.issue	10	en_US
dc.citation.spage	2764	en_US
dc.citation.epage	2770	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:000233154200020	-
dc.citation.woscount	6	-
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