標題: | Facile synthesis of a 56 pi-electron 1,2-dihydromethano-[60]PCBM and its application for thermally stable polymer solar cells |
作者: | Li, Chang-Zhi Chien, Shang-Chieh Yip, Hin-Lap Chueh, Chu-Chen Chen, Fang-Chung Matsuo, Yutaka Nakamura, Eiichi Jen, Alex K. -Y. 光電工程學系 顯示科技研究所 Department of Photonics Institute of Display |
公開日期: | 2011 |
摘要: | A facile synthesis was employed to make a 56 pi-electron methano-PC(61)BM with a very small 1,2-dihydromethano (CH(2)) group. This new fullerene derivative possesses high electron mobility (0.014 cm(2) V(-1) s(-1)) and higher LUMO energy level (0.15 eV) than PC(61)BM. Bulk hetero-junction devices based on using poly(3-hexylthiophene) and methano-PC(61)BM as active layer exhibited better performance and thermal stability than those using the PC(61)BM analogue. |
URI: | http://hdl.handle.net/11536/25923 http://dx.doi.org/10.1039/c1cc14446d |
ISSN: | 1359-7345 |
DOI: | 10.1039/c1cc14446d |
期刊: | CHEMICAL COMMUNICATIONS |
Volume: | 47 |
Issue: | 36 |
起始頁: | 10082 |
結束頁: | 10084 |
顯示於類別: | 期刊論文 |