Photodissociation dynamics of vinyl chloride investigated with a pulsed slit-jet and time-resolved Fourier-transform spectroscopy

Abstract

Following photodissociation of vinyl chloride seeded in a He supersonic jet at 193 nm, rotationally resolved infrared emission of HCl ( v) are recorded to yield nascent rotational and vibrational distributions. Preliminary results show that the rotational distribution of HCl free from rotational quenching deviates slightly from Boltzmann-type distribution and agrees well with trajectory calculations; a portion of the low-J component observed previously in a flow system is attributed to quenching. The implications for photodissociation dynamics are discussed.